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This suggestion was based on results observed with alkyl

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steroids drugs Reaction rates steroids, activation parameters and the temperature coefficients of these parameters have been determined and the results show that, for hydrolysis at the same temperature, the change in rate caused by replacing an alkyl chloride by the corresponding bromide arises almost entirely from a change in the activation energy; this applies to both S(_N)1 and S(_N)2 reactions. It has recently been suggested that the value of C(^+)/S(^+), where C(^+) is the heat capacity of activation, should be independent of the nature of the substrate in SNl solvolysis and that this ratio will have a lower value for solvolysis by mechanism S(_N)2 under the same experimental conditions. This suggestion was based on results observed with alkyl chlorides. steroids drugs

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